_SKIPNAVIGATION
ITA |
ENG
Personale
Recapiti
Pagina Cercachi
Italiano
Curriculum
Pubblicazioni
Insegnamenti
English
Curriculum
Roberto BINI
Ruolo attuale:
Professore Associato
SSD:
CHEM-02/A - Chimica fisica
Afferenza organizzativa:
Dipartimento di Chimica 'Ugo Schiff' - DICUS
Recapiti
0554573080 - 0554572489
roberto.bini(AT)unifi.it
Roberto BINI
Curriculum
CARRIERA SCIENTIFICA ED ACCADEMICA
Laurea in Chimica
all’Università di Firenze (1986),
PhD in Chimica
(curriculum Chimica-Fisica dello stato solido) all’Università di Firenze (1988-1991),
Dall’Ottobre 1991
Ricercatore
(Chimica-Fisica C02X) del Dipartimento di Chimica dell’Università di Firenze.
Dal Novembre 2000
Professore
associato
(Chimica-Fisica CHIM02) del Dipartimento di Chimica dell’Università di Firenze.
Dal 2000 coordinatore del gruppo di ricerca “
Matter Under Extreme Conditions
” all’ European Laboratory for non-linear Spectroscopy (LENS).
Dal 2010 membro del
Consiglio Direttivo del LENS
come rappresentante
dell’Università di Firenze.
Titolare dei corsi (Corso di Laurea in Chimica): 2000 - 2011: Spettroscopia Molecolare; 2001 - : Laboratorio Di Chimica Fisica I; 2009 - : Metodi sperimentali di indagine strutturale e dinamica.
Relatore di numerose Tesi in Chimica e Tesi di PhD in “Scienze dei Materiali” e “Atomic and Molecular Spectroscopy”, supervisore di numerosi progetti di post-dottorato.
ALTRE ATTIVITÃ:
Membro del review panel (2006 e 2011) per la valutazione delle beamlines (ID16 e ID27) specializzate in attività di alta pressione al European Synchrotron Research Facility (ESRF);
Membro del Physical Chemistry Directorate steering committee del Deep Carbon Observatory (
https://dco.gl.ciw.edu/
).
Coordinatore di numerosi progetti di ricerca finanziati da enti pubblici e compagnie private.
PREMI:
San Valentino d’Oro XXXI per la ricerca scientifica (2000);
Premio per la Chimica della rivista “Le Scienze” (2001);
Medaglia del Presidente della Repubblica per i risultati sperimentali ottenuti nello studio degli effetti della pressione sulle proprietà elettroniche e sulla reattività di cristalli molecolari (2001).
ATTIVITÀ DI RICERCA
L’attvità di ricerca è di tipo sperimentale e riguarda lo studio delle proprietà dinamiche e strutturali di sistemi molecolari in fase condensate mediante l’uso di tecniche spettroscopiche sia lineari che non-lineari. Negli ultimi anni la sua attenzione è stata diretta alla comprensione dei meccanismi che regolano la reattività indotta dalla pressione a livello molecolare in fluidi e cristalli molecolari utilizzando la tecnica della cella ad incidine di diamante (DAC) technique. I principali risultati ottenuti negli ultimi anni possono essere riassunti nel modo seguente:
realizzazione di un sitema di avanguardia basato sull’accoppiamento della DAC ad uno spettrofotometro FTIR per la misura di spettri infrarossi in funzione della pressione (P≤1 Mbar) e della temperatura (15-350 K).
monitoraggio della cinetica di transizioni di fase, trasformazioni molecolari e reazioni chimiche in fase cristallina indotte dalla pressione in sistemi molecolari modello (N
2
, O
2
, C
2
H
2
);
correlazione delle proprietà strutturali e dinamiche di cristalli al processo reattivo indotto dalla pressione, per la prima volta viene identificato e dimostrato il ruolo dei fononi reticolari nell’attivazione del processo reattivo;
applicazione di tecniche ottiche
non-lineari allo studio di campioni compressi nella DAC per una caratterizzazione diretta delle proprietà elettroniche in funzione della pressione;
uso combinato della radiazione e della pressione per indurre reazioni chimiche ed evidenziare
il ruolo degli stati elettronici eccitati nella reattività ad alta pressione;
applicazione di questi metodi alla sintesi di materiali estesi amorfi (benzene, CO
2
) polimerizzazione (polietilene, polibutadiene, poliacetilene) e reazioni in miscele (fluide, eterogenee e clatrati idrati) contenenti acqua e alcol semplici per la sintesi di idrogeno.
Ha pubblicato come autore principale o coautore più di 100 articoli nelle principali riviste internazionali
che trattano argomenti di tipo chimico-fisico e di fisica della materia condensata.
Roberto BINI
Pubblicazioni
Legenda
Contributo su rivista |
Articolo su libro |
Libro |
Contributo in atti di convegno (proceeding) |
Brevetto |
Curatela |
Altro |
Tesi di Dottorato
Berni, Selene; Scelta, Demetrio; Romi, Sebastiano; Fanetti, Samuele; Alabarse, Frederico; Pagliai, Marco; Bini, Roberto (2024). Exploring High‐Pressure Polymorphism in Carbonic Acid through Direct Synthesis from Carbon Dioxide Clathrate Hydrate. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, vol. 63, pp. 0-0, ISSN:1433-7851
DOI
Accesso ONLINE all'editore
Ceppatelli, Matteo; Serrano‐Ruiz, Manuel; Morana, Marta; Dziubek, Kamil; Scelta, Demetrio; Garbarino, Gaston; Poręba, Tomasz; Mezouar, Mohamed; Bini, Roberto; Peruzzini, Maurizio (2024). High‐pressure and high‐temperature synthesis of crystalline Sb3N5. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, pp. e202319278-1-e202319278-11, ISSN:1433-7851
DOI
Berni, Selene; Scelta, Demetrio; Romi, Sebastiano; Fanetti, Samuele; Alabarse, Frederico; Pagliai, Marco; Bini, Roberto (2024). Exploring High‐Pressure Polymorphism in Carbonic Acid through Direct Synthesis from Carbon Dioxide Clathrate Hydrate. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, vol. 63, pp. e202403953-1-e202403953-8, ISSN:1433-7851
DOI
Sukserm, Akkarach; Ceppatelli, Matteo; Serrano-Ruiz, Manuel; Scelta, Demetrio; Dziubek, Kamil; Morana, Marta; Bini, Roberto; Peruzzini, Maurizio; Bovornratanaraks, Thiti; Pinsook, Udomsilp; Scandolo, Sandro (2024). Stability, Chemical Bonding, and Electron Lone Pair Localization in AsN at High Pressure by Density Functional Theory Calculations. INORGANIC CHEMISTRY, vol. 63, pp. 8142-8154, ISSN:0020-1669
DOI
Fanetti, Samuele; Romi, Sebastiano; Berretti, Enrico; Hanfland, Michael; Mijit, Emin; Alabarse, Frederico; Dalladay-Simpson, Philip; Gorelli, Federico; Bini, Roberto; Santoro, Mario (2023). High pressure decomposition of a sandwich compound. THE JOURNAL OF CHEMICAL PHYSICS, vol. 159, pp. 134502-1-134502-11, ISSN:0021-9606
DOI
Accesso ONLINE all'editore
Agati, M; Fanetti, S; Bini, R (2023). Pressure induced modification of the electronic properties of stilbene by two-photon spectroscopy. THE JOURNAL OF CHEMICAL PHYSICS, vol. 158, pp. 034505-1-034505-8, ISSN:0021-9606
DOI
Berni, S; Scelta, D; Fanetti, S; Bini, R (2023). High pressure behavior of ethylene and water: From clathrate hydrate to polymerization in solid ice mixtures. THE JOURNAL OF CHEMICAL PHYSICS, vol. 158, pp. 064505-1-064505-11, ISSN:0021-9606
DOI
Agati, Milo; Romi, Sebastiano; Fanetti, Samuele; Bini, Roberto (2023). High-pressure structure and reactivity of crystalline bibenzyl: Insights and prospects for the synthesis of functional double-core carbon nanothreads. THE JOURNAL OF CHEMICAL PHYSICS, vol. 159, pp. 244507-1-244507-10, ISSN:0021-9606
DOI
Berni, Selene; Scelta, Demetrio; Fanetti, Samuele; Bini, Roberto (2023). Complexities in the structural evolution with pressure of water-ammonia mixtures. THE JOURNAL OF CHEMICAL PHYSICS, vol. 158, pp. 184302_1-184302_10, ISSN:0021-9606
DOI
Scelta, Demetrio; Ceppatelli, Matteo; Bini, Roberto; Pakhomova, Anna; Garbarino, Gaston; Mezouar, Mohamed; Santoro, Mario (2023). High temperature decomposition of polymeric carbon monoxide at pressures up to 120 GPa. THE JOURNAL OF CHEMICAL PHYSICS, vol. 159, pp. 0-0, ISSN:0021-9606
DOI
Fanetti S.; Romi S.; Crichton W.; Rosenthal A.; Scelta D.; Alabarse F.; Bini R.; Santoro M. (2023). Quasi-isotropic high pressure, large volume synthesis of a polymeric composite incorporating diamond-like carbon nano-threads. DIAMOND AND RELATED MATERIALS, vol. 136, pp. 109912_1-109912_8, ISSN:0925-9635
DOI
K. Dziubek, M. Ceppatelli, D. Scelta, M. Serrano-Ruiz, M. Morana, V. Svitlyk, G. Garbarino, T. Poręba, M. Mezouar, M. Peruzzini, R. Bini (2022). Binary arsenic nitride synthesized from elements under pressure. In: ECM33, International Union of Crystallography, vol. 78, pp. 0-0.
Ceppatelli, Matteo; Scelta, Demetrio; Serrano-Ruiz, Manuel; Dziubek, Kamil; Izquierdo-Ruiz, Fernando; Recio, J Manuel; Garbarino, Gaston; Svitlyk, Volodymyr; Mezouar, Mohamed; Peruzzini, Maurizio; Bini, Roberto (2022). High-Pressure and High-Temperature Chemistry of Phosphorus and Nitrogen: Synthesis and Characterization of α- and γ-P3N5. INORGANIC CHEMISTRY, vol. 61, pp. 12165-12180, ISSN:0020-1669
DOI
Santoro M.; Bini R.; Ceppatelli M.; Garbarino G.; Gorelli F.A.; Hanfland M.; Scelta D. (2022). High Pressure Structural Changes in Amorphous Polymeric Carbon Monoxide by Combined Infrared Spectroscopy and X-ray Diffraction. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 126, pp. 11840-11845, ISSN:1932-7447
DOI
Ceppatelli M.; Scelta D.; Serrano-Ruiz M.; Dziubek K.; Morana M.; Svitlyk V.; Garbarino G.; Poreba T.; Mezouar M.; Peruzzini M.; Bini R. (2022). Single-Bonded Cubic AsN from High-Pressure and High-Temperature Chemical Reactivity of Arsenic and Nitrogen. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, vol. 61, pp. e202114191_1-e202114191_9, ISSN:1433-7851
DOI
Pesach, Asaf; Nguyen, Long; Gorelli, Federico A.; Bini, Roberto; Hevroni, Refael; Nikolaevsky, Mark; dos Santos, Antonio M.; Tulk, Christopher A.; Molaison, Jamie J.; Shuker, Reuben; Melchior, Aviva; Caspi, El'ad N.; Salem, Ran; Makov, Guy; Sterer, Eran (2022). The mechanism behind SnO metallization under high pressure. RESULTS IN PHYSICS, vol. 39, pp. 0-0, ISSN:2211-3797
DOI
Accesso ONLINE all'editore
Romi, Sebastiano; Fanetti, Samuele; Alabarse, Frederico; Mio, Antonio M; Haines, Julien; Bini, Roberto (2022). Towards custom built double core carbon nanothreads using stilbene and pseudo-stilbene type systems. NANOSCALE, pp. 4614-4625, ISSN:2040-3372
DOI
Romi S.; Fanetti S.; Alabarse F.G.; Bini R.; Santoro M. (2022). High-Pressure Synthesis of 1D Low-Bandgap Polymers Embedded in Diamond-like Carbon Nanothreads. CHEMISTRY OF MATERIALS, vol. 34, pp. 2422-2428, ISSN:0897-4756
DOI
Scelta, Demetrio; Fanetti, Samuele; Berni, Selene; Ceppatelli, Matteo; Bini, Roberto (2022). Addressing Open Issues about the Structural Evolution of Methane Clathrate Hydrate. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 126, pp. 19487-19495, ISSN:1932-7447
DOI
Santoro M.; Morana M.; Scelta D.; Rouquette J.; Dziubek K.; Gorelli F.A.; Bini R.; Garbarino G.; Van Der Lee A.; Di Renzo F.; Coasne B.; Haines J. (2021). Insertion of Oxygen and Nitrogen in the Siliceous Zeolite TON at High Pressure. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 125, pp. 19517-19524, ISSN:1932-7447
DOI
Romi S.; Fanetti S.; Alabarse F.; Bini R. (2021). Structure-Reactivity Relationship in the High-Pressure Formation of Double-Core Carbon Nanothreads from Azobenzene Crystal. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 125, pp. 17174-17182, ISSN:1932-7447
DOI
Scelta, Demetrio; Dziubek, Kamil F.; Ende, Martin; Miletich, Ronald; Mezouar, Mohamed; Garbarino, Gaston; Bini, Roberto (2021). Extending the Stability Field of Polymeric Carbon Dioxide Phase V beyond the Earth’s Geotherm. PHYSICAL REVIEW LETTERS, vol. 126, pp. 065701-1-065701-7, ISSN:0031-9007
DOI
Calvagna C.; Lapini A.; Taschin A.; Fanetti S.; Pagliai M.; Bartolini P.; Bini R.; Righini R.; Torre R. (2021). Modification of local and collective dynamics of water in perchlorate solution, induced by pressure and concentration. JOURNAL OF MOLECULAR LIQUIDS, vol. 337, pp. 116273-1-116273-14, ISSN:0167-7322
DOI
Gunka P.A.; Olejniczak A.; Fanetti S.; Bini R.; Collings I.E.; Svitlyk V.; Dziubek K.F. (2021). Crystal Structure and Non-Hydrostatic Stress-Induced Phase Transition of Urotropine Under High Pressure. CHEMISTRY-A EUROPEAN JOURNAL, vol. 27, pp. 1094-1102, ISSN:0947-6539
DOI
Romi S.; Fanetti S.; Alabarse F.; Mio A.M.; Bini R. (2021). Synthesis of double core chromophore-functionalized nanothreads by compressing azobenzene in a diamond anvil cell. CHEMICAL SCIENCE, vol. 12, pp. 7048-7057, ISSN:2041-6520
DOI
Zhang, Huichao; Tóth, Ondrej; Liu, Xiao-Di; Bini, Roberto; Gregoryanz, Eugene; Dalladay-Simpson, Philip; De Panfilis, Simone; Santoro, Mario; Gorelli, Federico Aiace; Martoňák, Roman (2020). Pressure-induced amorphization and existence of molecular and polymeric amorphous forms in dense SO2. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, vol. 117, pp. 8736-8742, ISSN:0027-8424
DOI
Scelta D.; Baldassarre A.; Serrano-Ruiz M.; Marchuk A.; Vogel S.; Schnick W.; Peruzzini M.; Bini R.; Ceppatelli M. (2020). High-Pressure Synthesis of Cyclic Phosphazenes by Near-UV Photoinduced Reactivity of NH3 and Elemental Phosphorus. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 124, pp. 4308-4319, ISSN:1932-7447
DOI
Fanetti S.; Santoro M.; Alabarse F.; Enrico B.; Bini R. (2020). Modulating the H-bond strength by varying the temperature for the high pressure synthesis of nitrogen rich carbon nanothreads. NANOSCALE, vol. 12, pp. 5233-5242, ISSN:2040-3364
DOI
Fanetti, Samuele; Scelta, Demetrio; Bini, Roberto (2020). Growth Dynamics of Crystalline Ar Hydrate. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 124, pp. 10159-10166, ISSN:1932-7447
DOI
Friedrich, Alexandra; Collings, Ines E; Dziubek, Kamil F; Fanetti, Samuele; Radacki, Krzysztof; Ruiz-Fuertes, Javier; Pellicer-Porres, Julio; Hanfland, Michael; Sieh, Daniel; Bini, Roberto; Clark, Stewart J; Marder, Todd B (2020). Pressure-Induced Polymerization of Polycyclic Arene-Perfluoroarene Cocrystals: Single Crystal X-ray Diffraction Studies, Reaction Kinetics, and Design of Columnar Hydrofluorocarbons. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 142, pp. 18907-18923, ISSN:0002-7863
DOI
Ceppatelli, Matteo; Scelta, Demetrio; Serrano-Ruiz, Manuel; Dziubek, Kamil; Garbarino, Gaston; Jacobs, Jeroen; Mezouar, Mohamed; Bini, Roberto; Peruzzini, Maurizio (2020). High pressure synthesis of phosphine from the elements and the discovery of the missing (PH3)2H2 tile. NATURE COMMUNICATIONS, vol. 11, pp. 6125-1-6125-11, ISSN:2041-1723
DOI
Accesso ONLINE all'editore
Lamaignere L.; Toci G.; Patrizi B.; Vannini M.; Pirri A.; Fanetti S.; Bini R.; Mennerat G.; Melninkaitis A.; Lukas L.; Hein J. (2020). Determination of non-linear refractive index of laser crystals and ceramics via different optical techniques. OPTICAL MATERIALS. X, vol. 8, pp. 100065-1-100065-12, ISSN:2590-1478
DOI
Taschin, Andrea; Bartolini, Paolo; Fanetti, Samuele; Lapini, Andrea; Citroni, Margherita; Righini, Roberto; Bini, Roberto; Torre, Renato (2020). Pressure Effects on Water Dynamics by Time-Resolved Optical Kerr Effect. THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS, vol. 11, pp. 3063-3068, ISSN:1948-7185
DOI
Romi S.; Fanetti S.; Bini R. (2020). Accessing the Activation Mechanisms of Ethylene Photo-Polymerization under Pressure by Transient Infrared Absorption Spectroscopy. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 124, pp. 8149-8157, ISSN:1520-6106
DOI
Santoro, Mario; Gorelli, Federico A.; Dziubek, Kamil; Scelta, Demetrio; Bini, Roberto (2020). Structural and Chemical Modifications of Carbon Dioxide on Transport to the Deep Earth. In: Mario Santoro, Federico A. Gorelli, Kamil Dziubek, Demetrio Scelta, Roberto Bini. Carbon in Earth's Interior, pp. 55-65 Craig E. Manning Jung‐Fu Lin Wendy L. Mao, ISBN:9781119508267.
DOI
Accesso ONLINE all'editore
Faria, Luiz F. O.*; Nobrega, Marcelo M.; Falsini, Naomi; Fanetti, Samuele; Temperini, Marcia L. A.; Bini, Roberto; Ribeiro, Mauro C. C. (2019). Structure and Reactivity of the Ionic Liquid 1-Allyl-3-methylimidazolium Iodide under High Pressure. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 123, pp. 1822-1830, ISSN:1520-6106
DOI
Accesso ONLINE all'editore
Peruzzini, Maurizio*; Bini, Roberto; Bolognesi, Margherita; Caporali, Maria; Ceppatelli, Matteo; Cicogna, Francesca; Coiai, Serena; Heun, Stefan; Ienco, Andrea; Benito, Iñigo Iglesias; Kumar, Abhishek; Manca, Gabriele; Passaglia, Elisa; Scelta, Demetrio; Serrano-Ruiz, Manuel; Telesio, Francesca; Toffanin, Stefano; Vanni, Matteo (2019). A Perspective on Recent Advances in Phosphorene Functionalization and Its Applications in Devices. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. 2019, pp. 1476-1494, ISSN:1434-1948
DOI
Accesso ONLINE all'editore
Santoro, Mario; Dziubek, Kamil; Scelta, Demetrio; Morana, Marta; Gorelli, Federico A.; Bini, Roberto; Hanfland, Michael; Rouquette, Jérôme; di Renzo, Francesco; Haines, Julien (2019). Dense, Subnano Phase of Clustered O2. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 123, pp. 9651-9657, ISSN:1932-7447
DOI
Fanetti S.; Nobrega M.M.; Dziubek K.; Citroni M.; Sella A.; McMillan P.F.; Hanfland M.; Bini R. (2019). Structure and reactivity of 2,4,6-tricyano-1,3,5-triazine under high-pressure conditions. CRYSTENGCOMM, vol. 21, pp. 4493-4500, ISSN:1466-8033
DOI
Accesso ONLINE all'editore
Fanetti S.; Falsini N.; Bartolini P.; Citroni M.; Lapini A.; Taschin A.; Bini R. (2019). Superheating and Homogeneous Melting Dynamics of Bulk Ice. THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS, vol. 10, pp. 4517-4522, ISSN:1948-7185
DOI
Accesso ONLINE all'editore
Scelta, Demetrio; Ceppatelli, Matteo; Ballerini, Riccardo; Hajeb, Ahmed; Peruzzini, Maurizio; Bini, Roberto (2018). Spray-loading: A cryogenic deposition method for diamond anvil cell. REVIEW OF SCIENTIFIC INSTRUMENTS, vol. 89, pp. 053903-1-053903-5, ISSN:0034-6748
DOI
Fanetti, Samuele; Nobrega, Marcelo M.; Teixeira-Neto, Erico; Temperini, Marcia L. A.; Bini, Roberto (2018). Effect of Structural Anisotropy in High-Pressure Reaction of Aniline. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 122, pp. 29158-29164, ISSN:1932-7447
DOI
Accesso ONLINE all'editore
Nobrega, Marcelo M.; Teixeira-Neto, Erico; Cairns, Andrew B.; Temperini, Marcia L. A.; Bini, Roberto (2018). One-dimensional diamondoid polyaniline-like nanothreads from compressed crystal aniline. CHEMICAL SCIENCE, vol. 9, pp. 254-260, ISSN:2041-6520
DOI
Accesso ONLINE all'editore
Roberto Bini, Matteo Ceppatelli, Demetrio Scelta, Adhara Baldassarre, Kamil Dziubek, Maurizio Peruzzini, Manuel Serrano-Ruiz, Andrew B. Cairns (2018). The p-sc structure in phosphorus: Bringing order to the high pressure phases of group 15 elements. CHEMICAL COMMUNICATIONS, vol. 54, pp. 10554-10557, ISSN:1359-7345
DOI
Dziubek, Kamil F; Ende, Martin; Scelta, Demetrio; Bini, Roberto; Mezouar, Mohamed; Garbarino, Gaston; Miletich, Ronald (2018). Crystalline polymeric carbon dioxide stable at megabar pressures. NATURE COMMUNICATIONS, vol. 9, pp. 3148-1-3148-6, ISSN:2041-1723
DOI
Fanetti, Samuele; Citroni, Margherita; Dziubek, Kamil; Nobrega, Marcelo Medre; Bini, Roberto (2018). The role of H-bond in the high-pressure chemistry of model molecules. JOURNAL OF PHYSICS. CONDENSED MATTER, vol. 30, pp. 094001-1-094001-8, ISSN:0953-8984
DOI
Accesso ONLINE all'editore
Lapini, Andrea; Fanetti, Samuele; Citroni, Margherita; Bini, Roberto; Gilbert, Charles-Olivier; Rondeau-Gagné, Simon; Morin, Jean-Francois (2018). Topochemical Polymerization of Phenylacetylene Macrocycles under Pressure. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 122, pp. 20034-20039, ISSN:1932-7447
DOI
Jarzembska, Katarzyna N; Kamiński, Radosław; Dziubek, Kamil F; Citroni, Margherita; Paliwoda, Damian; Durka, Krzysztof; Fanetti, Samuele; Bini, Roberto (2018). Impact of High Pressure on Metallophilic Interactions and Its Consequences for Spectroscopic Properties of a Model Tetranuclear Silver(I)-Copper(I) Complex in the Solid State. INORGANIC CHEMISTRY, vol. 57, pp. 8509-8520, ISSN:0020-1669
DOI
Fanetti, Samuele; Citroni, Margherita; Falsini, Naomi; Bini, Roberto (2018). The Photochemistry of Crystalline Nitromethane under Static Pressure. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 122, pp. 2023-2031, ISSN:1932-7447
DOI
Accesso ONLINE all'editore
Nobrega, Marcelo M.; Temperini, Marcia L. A.; Bini, Roberto (2017). Probing the Chemical Stability of Aniline under High Pressure. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 121, pp. 7495-7501, ISSN:1932-7447
DOI
Citroni, Margherita; Fanetti, Samuele; Falsini, Naomi; Foggi, Paolo; Bini, Roberto (2017). Melting dynamics of ice in the mesoscopic regime. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, vol. 114, pp. 5935-5940, ISSN:0027-8424
DOI
Accesso ONLINE all'editore
Dziubek, Kamil; Citroni, Margherita; Fanetti, Samuele; Cairns, Andrew B.; Bini, Roberto (2017). High-Pressure High-Temperature Structural Properties of Urea. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 121, pp. 2380-2387, ISSN:1932-7447
DOI
Dziubek, Kamil; Citroni, Margherita; Fanetti, Samuele; Cairns, Andrew B.; Bini, Roberto (2017). Synthesis of High-Quality Crystalline Carbon Nitride Oxide by Selectively Driving the High-Temperature Instability of Urea with Pressure. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 121, pp. 19872-19879, ISSN:1932-7447
DOI
Scelta, Demetrio; Baldassarre, Adhara; Serrano-Ruiz, Manuel; Dziubek, Kamil; Cairns, Andrew B.; Peruzzini, Maurizio; Bini, Roberto; Ceppatelli, Matteo (2017). Interlayer Bond Formation in Black Phosphorus at High Pressure. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, vol. 56, pp. 14135-14140, ISSN:1433-7851
DOI
Accesso ONLINE all'editore
Santoro, Mario; Gorelli, Federico A.; Bini, Roberto; Haines, Julien (2017). Intermolecular Interactions in Highly Disordered, Confined Dense N2. THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS, vol. 8, pp. 2406-2411, ISSN:1948-7185
DOI
Accesso ONLINE all'editore
Santoro, Mario; Gorelli, Federico A.; Bini, Roberto; Salamat, Ashkan; Garbarino, Gaston; Levelut, Claire; Cambon, Olivier; Haines, Julien (2016). Correspondence: Reply to Strongly-driven Re+CO2 redox reaction at high-pressure and high-temperature. NATURE COMMUNICATIONS, vol. 7, pp. 13538-1-13538-2, ISSN:2041-1723
DOI
Accesso ONLINE all'editore
Lapini, Andrea; Pagliai, Marco; Fanetti, Samuele; Citroni, Margherita; Scandolo, Sandro; Bini, Roberto; Righini, Roberto (2016). Pressure Dependence of Hydrogen-Bond Dynamics in Liquid Water Probed by Ultrafast Infrared Spectroscopy. THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS, vol. 7, pp. 3579-3584, ISSN:1948-7185
DOI
Accesso ONLINE all'editore
Ceppatelli, Matteo; Scelta, Demetrio; Tuci, Giulia; Giambastiani, Giuliano; Hanfland, Michael; Bini, Roberto (2016). High-Pressure Chemistry of Graphene Oxide in the Presence of Ar, N2, and NH3. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 120, pp. 5174-5187, ISSN:1932-7447
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Faria, Luiz F. O.; Nobrega, Marcelo M.; Temperini, Marcia L. A.; Bini, Roberto; Ribeiro, Mauro C. C (2016). Triggering the Chemical Instability of an Ionic Liquid under High Pressure. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 120, pp. 9097-9102, ISSN:1520-6106
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Santoro, Mario; Scelta, Demetrio; Dziubek, Kamil; Ceppatelli, Matteo; Gorelli, Federico A.; Bini, Roberto; Garbarino, Gaston; Thibaud, Jean-Marc; Di Renzo, Francesco; Cambon, Olivier; Hermet, Patrick; Rouquette, Jerome; Van Der Lee, Arie; Haines, Julien (2016). Synthesis of 1D Polymer/Zeolite Nanocomposites under High Pressure. CHEMISTRY OF MATERIALS, vol. 28, pp. 4065-4071, ISSN:0897-4756
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Scelta, Demetrio; Ceppatelli, Matteo; Bini, Roberto (2016). Pressure induced polymerization of fluid ethylene. THE JOURNAL OF CHEMICAL PHYSICS, vol. 145, pp. 164504-1-164504-7, ISSN:0021-9606
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Citroni, Margherita; Fanetti, Samuele; Bazzicalupi, Carla; Dziubek, Kamil; Pagliai, Marco; Nobrega, Marcelo Medre; Mezouar, Mohamed; Bini, Roberto (2015). Structural and Electronic Competing Mechanisms in the Formation of Amorphous Carbon Nitride by Compressings-Triazine. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 119, pp. 28560-28569, ISSN:1932-7447
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Mio, A.M.; Privitera, S.; D'Arrigo, G.; Ceppatelli, M.; Gorelli, F.; Santoro, M.; Miritello, M.; Bini, R.; Rimini, E. (2015). Structural transformations in Ge2Sb2Te5 under high pressure and temperature. JOURNAL OF APPLIED PHYSICS, vol. 118, pp. 064503-1-064503-5, ISSN:0021-8979
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Ceppatelli, Matteo; Pagliai, Marco; Bini, Roberto; Jodl, Hans J. (2015). High-pressure photoinduced synthesis of polynitrogen in δ and ε nitrogen crystals substitutionally doped with CO. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 119, pp. 130-140, ISSN:1932-7447
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Santoro, Mario; Dziubek, Kamil; Scelta, Demetrio; Ceppatelli, Matteo; Gorelli, Federico A.; Bini, Roberto; Thibaud, Jean-Marc; Di Renzo, Francesco; Cambon, Olivier; Rouquette, Jerome; Hermet, Patrick; van der Lee, Arie; Haines, Julien (2015). High Pressure Synthesis of All-Transoid Polycarbonyl [—(C═O)—]n in a Zeolite. CHEMISTRY OF MATERIALS, vol. 27, pp. 6486-6489, ISSN:0897-4756
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Ceppatelli, Matteo; Scelta, Demetrio; Tuci, Giulia; Giambastiani, Giuliano; Hanfland, Michael; Bini, Roberto (2015). Lattice expansion of graphite oxide by pressure induced insertion of liquid ammonia. CARBON, vol. 93, pp. 484-491, ISSN:0008-6223
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M. Citroni;S. Fanetti;B. Guigue;P. Bartolini;A. Taschin;A. Lapini;P. Foggi;R. Bini (2014). Picosecond optical parametric generator and amplifier for large temperature-jump. OPTICS EXPRESS, vol. 22, pp. 30047-30052, ISSN:1094-4087
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Roberto Bini; Vincenzo Schettino (2014). Materials Under Extreme Conditions - Molecular Crystals at High Pressure. Londra: Imperial College Press, ISBN:9781848163058
Samuele Fanetti; Marco Pagliai; Margherita Citroni; Andrea Lapini; Sandro Scandolo; Roberto Righini; Roberto Bini (2014). Connecting the Water Phase Diagram to the Metastable Domain: High-Pressure Studies in the Supercooled Regime. THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS, vol. 5, pp. 3804-3809, ISSN:1948-7185
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Samuele Fanetti; Andrea Lapini; Marco Pagliai; Margherita Citroni; Mariangela Di Donato; Sandro Scandolo; Roberto Righini; Roberto Bini (2014). Structure and Dynamics of Low-Density and High-Density Liquid Water at High Pressure. THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS, vol. 5, pp. 235-240, ISSN:1948-7185
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M. Ceppatelli; S. Fanetti; R. Bini; M. Caporali; M. Peruzzini (2014). High pressure chemistry of red phosphorus by photo-activated simple molecules. JOURNAL OF PHYSICS. CONFERENCE SERIES, vol. 500, pp. 022008-1-022008-6, ISSN:1742-6596
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D. Scelta; M. Ceppatelli; M. Santoro; Roberto Bini; F. A. Gorelli; A. Perucchi; M. Mezouar; A. van der Lee; J. Haines (2014). High pressure polymerization in a confined space: conjugated chain/zeolite nano-composites. CHEMISTRY OF MATERIALS, vol. 26, pp. 2249-2255, ISSN:0897-4756
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M. Ceppatelli; F. A. Gorelli; J. Haines; M. Santoro; R. Bini (2014). Probing high-pressure reactions in heterogeneous materials by Raman spectroscopy. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, vol. 229, pp. 83-91, ISSN:0044-2968
DOI
M. Santoro; F.A. Gorelli; R. Bini; J. Haines; O. Cambon; C. Levelut; A. van der Lee; G. Garbarino (2014). High pressure synthesis of novel, zeolite based nano-composite materials. JOURNAL OF PHYSICS. CONFERENCE SERIES, vol. 500, pp. 022010-1-022010-8, ISSN:1742-6596
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Margherita Citroni;Samuele Fanetti;Roberto Bini (2014). Pressure and Laser-Induced Reactivity in Crystalline s-Triazine. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 118, pp. 10284-10290, ISSN:1932-7447
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Samuele Fanetti;Margherita Citroni;Roberto Bini (2014). Tuning the Aromaticity of s-Triazine in the Crystal Phase by Pressure. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 118, pp. 13764-13768, ISSN:1932-7447
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M. Citroni; S. Fanetti; P. Foggi; R. Bini (2014). Non-linear optical properties of molecular systems under high static pressures. JOURNAL OF PHYSICS. CONFERENCE SERIES, vol. 500, pp. 022003-1-022003-8, ISSN:1742-6596
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M. Ceppatelli;Roberto Bini (2014). Light-Induced Catalyst and Solvent-Free High Pressure Synthesis of High Density Polyethylene at Ambient Temperature. MACROMOLECULAR RAPID COMMUNICATIONS, vol. 35, pp. 787-793, ISSN:1022-1336
DOI
Mario Santoro;Federico A. Gorelli;Roberto Bini;Ashkan Salamat;Gaston Garbarino;Claire Levelut;Olivier Cambon;Julien Haines (2014). Carbon enters silica forming a cristobalite-type CO2-SiO2 solid solution. NATURE COMMUNICATIONS, vol. 5, pp. 1-5, ISSN:2041-1723
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Marcelo M. Nobrega; Matteo Ceppatelli; Marcia L. A. Temperini; Roberto Bini (2014). Pressure-Induced Reactivity in the Emeraldine Salt and Base Forms of Polyaniline Probed by FTIR and Raman. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 118, pp. 27559-27566, ISSN:1932-7447
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Samuele Fanetti; Margherita Citroni; Lorenzo Malavasi; Gianluca A. Artioli; Paolo Postorino; Roberto Bini (2013). High-Pressure Optical Properties and Chemical Stability of Picene. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 117, pp. 5343-5351, ISSN:1932-7447
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Matteo Ceppatelli; Samuele Fanetti; Roberto Bini (2013). Photoinduced Reactivity of Red Phosphorus and Ethanol at High Pressure. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 117, pp. 13129-13135, ISSN:1932-7447
DOI
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Mario Santoro;Federico A. Gorelli; Roberto Bini; Julien Haines; Arie van der Lee (2013). High-pressure synthesis of a polyethylene/zeolite nano-composite material. NATURE COMMUNICATIONS, vol. 4, pp. 1557-1-1557-6, ISSN:2041-1723
DOI
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Matteo Ceppatelli; Roberto Bini; Maria Caporali; Maurizio Peruzzini (2013). High-Pressure Chemistry of Red Phosphorus and Water under Near-UV Irradiation. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, vol. 52, pp. 2313-2317, ISSN:1433-7851
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S. Fanetti; M. Ceppatelli; M. Citroni; R. Bini (2012). High-pressure photoinduced reactivity of CH3OH and CD3OH. JOURNAL OF PHYSICAL CHEMISTRY. C, vol. 116, pp. 2108-2115, ISSN:1932-7447
R. Bini; M. Ceppatelli; M. Citroni; V. Schettino (2012). From simple to complex and backwards. Chemical reactions under very high pressure. CHEMICAL PHYSICS, vol. 398, pp. 262-268, ISSN:0301-0104
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Samuele Fanetti; Margherita Citroni; Roberto Bini; Lorenzo Malavasi; Gianluca A. Artioli, Paolo Postorino (2012). HOMO-LUMO transitions in solvated and crystalline picene. THE JOURNAL OF CHEMICAL PHYSICS, vol. 137, pp. 224506-1-224506-7, ISSN:0021-9606
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M. Santoro; F. A. Gorelli; R. Bini; J. Haines; O. Cambon; C. Levelut; J.A. Montoya; S. Scandolo (2012). Partially collapsed cristobalite structure inthe non molecular phase V in CO2. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, vol. 109, pp. 5176-5179, ISSN:1091-6490
R. Bini (2011). The role of high-pressure in the reactivity of simplemolecules: implications in prebiotic chemistry. RENDICONTI LINCEI. SCIENZE FISICHE E NATURALI, vol. 22, pp. 385-393, ISSN:2037-4631
S. Fanetti; M. Citroni; R. Bini (2011). Pressure-induced fluorescence of pyridine. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 115, pp. 12051-12058, ISSN:1520-6106
M. Ceppatelli; M. Frediani; R. Bini (2011). High pressure reactivity of L,L-lactide. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 115, pp. 2173-2184, ISSN:1520-6106
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M. Ceppatelli; R. Bini; V. Schettino (2011). High-pressure reactivity of clathrate hydrates by two-photon dissociation of water. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, vol. 13, pp. 1264-1275, ISSN:1463-9076
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S. Fanetti; M. Citroni; R. Bini (2011). Structure and reactivity of pyridine crystal under pressure. THE JOURNAL OF CHEMICAL PHYSICS, vol. 134, pp. 204504-1-204504-9, ISSN:0021-9606
S. Fanetti; M. Ceppatelli; M. Citroni; R. Bini (2011). Changing the dissociative character of the lowest excited state ofethanol by pressure. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 115, pp. 15236-15240, ISSN:1520-6106
Margherita Citroni; Roberto Bini; Marco Pagliai; Gianni Cardini; Vincenzo Schettino (2010). Nitromethane decomposition under high static pressure. THE JOURNAL OF PHYSICAL CHEMISTRY. B, vol. 114, pp. 9420-9428, ISSN:1520-5207
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M. Ceppatelli; S. Fanetti; M. Citroni; R. Bini (2010). Photoinduced reactivity of liquid ethanol at high pressure. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 114, pp. 15437-15444, ISSN:1520-6106
V. M. Giordano; F. Datchi; F. A. Gorelli; R. Bini (2010). Equation of state and anharmonicity of carbon dioxide phase Iup to 12 GPa and 800 K. THE JOURNAL OF CHEMICAL PHYSICS, vol. 133, pp. 144501-1-144501-9, ISSN:0021-9606
L. Fontana; M. Santoro; R. Bini; D.Q. Vinh; S. Scandolo (2010). High pressure vibrational properties of polyethylene. THE JOURNAL OF CHEMICAL PHYSICS, vol. 133, pp. 204502-1-204502-2, ISSN:0021-9606
M. Citroni; B. Costantini; R. Bini; V. Schettino (2009). Crystalline Indole at High Pressure: Chemical Stability, Electronic, and Vibrational Properties. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 113, pp. 13526-13535, ISSN:1520-6106
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M. Ceppatelli; R. Bini; V. Schettino (2009). High-Pressure Reactivity of Model Hydrocarbons Driven by Near-UV Photodissociation of Water. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 113, pp. 14640-14647, ISSN:1520-6106
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V.Schettino; R.Bini; G.Cardini; M.Ceppatelli; M.Citroni; M.Pagliai (2009). Spectroscopy and monitoring of high pressure phenomena. JOURNAL OF MOLECULAR STRUCTURE, vol. 924-926, pp. 2-8, ISSN:0022-2860
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M.Ceppatelli; A.Serdyukov; R.Bini; H.J.Jodi (2009). Pressure Induced Reactivity of Solid CO by FTIR Studies. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 113, pp. 6652-6660, ISSN:1520-6106
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M.Ceppatelli; R.Bini; V.Schettino (2009). High-pressure photodissociation of water as a tool for hydrogen synthesis and fundamental chemistry. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, vol. 106, pp. 11454-11459, ISSN:0027-8424
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M. Citroni; F. Datchi; R. Bini; M. Di Vaira; P. Pruzan; B. Canny; V. Schettino (2008). Crystal structure of nitromethane up to the reaction threshold pressure. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 112, pp. 1095-1103, ISSN:1520-6106
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V.Schettino; R.Bini; G.Cardini; M.Ceppatelli; M.Citroni; M.Pagliai (2008). Solid-state transitions and chemical reactions at high pressure. IL NUOVO CIMENTO DELLA SOCIETÀ ITALIANA DI FISICA. B, GENERAL PHYSICS, RELATIVITY, ASTRONOMY AND MATHEMATICAL PHYSICS AND METHODS, vol. 123, pp. 1399-1414, ISSN:1594-9982
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M. Citroni; R. Bini; P. Foggi; V. Schettino (2008). Role of excited electronic states in the high-pressure amorphization of benzene. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, vol. 105, pp. 7658-7663, ISSN:0027-8424
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F. Gorelli; M. Santoro; R. Bini; L. Ulivi (2008). Extended infrared absorption spectroscopy study of the magnetic properties of solid oxygen at high-pressure and low-temperature. PHYSICAL REVIEW. B, CONDENSED MATTER AND MATERIALS PHYSICS, vol. 77, pp. 132103-1-132103-4, ISSN:1098-0121
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V. Schettino; R. Bini; M. Ceppatelli; M. Citroni (2008). Activation and control of chemical reactions at very high pressure. PHYSICA SCRIPTA, vol. 78, pp. 058104-1-058104-6, ISSN:0031-8949
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R. Bini; P. Bouvier (2007). Guest editor's note. PHASE TRANSITIONS, vol. 80, pp. 999-1000, ISSN:0141-1594
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V. SCHETTINO; R. BINI (2007). Constraining molecules at the closest approach: chemistry at high pressure. CHEMICAL SOCIETY REVIEWS, vol. 36, pp. 869-880, ISSN:0306-0012, Royal Society of Chemistry:Thomas Graham House, Science Park, Cambridge CB4 0WF United Kingdom:011 44 1223 432360, EMAIL: sales@rsc.org, INTERNET: http://www.rsc.org, http://www.chensoc.org, Fax: 011 44 1223 423429:
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L. Fontana; D. Q. Vinh; M. Santoro; S. Scandolo; F. A. Gorelli; R. Bini; M. Hanfland (2007). High-pressure crystalline polyethylene studied by x-ray diffraction and ab initio simulations. PHYSICAL REVIEW. B, CONDENSED MATTER AND MATERIALS PHYSICS, vol. 75, pp. 174112-1-174112-11, ISSN:1098-0121
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L. Ciabini; F.A Gorelli; M. Santoro; R. Bini; V. Schettino; S. Raugei (2007). Triggering dynamics of the high-pressure benzene amorphization. NATURE MATERIALS, vol. 6, pp. 39-43, ISSN:1476-1122
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M. Citroni; M. Ceppatelli; R. Bini; V. Schettino (2007). Dimerization and polymerization of isoprene at high pressures. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 111, pp. 3910-3917, ISSN:1520-6106
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E. GREGORYANZ; C. SANLOUP; R. BINI; J. KREUTZ; H. J. JODL; M. SOMAYAZULU; H. K. MAO AND R. J. HEMLEY (2006). On the ε- ζ transition of nitrogen. THE JOURNAL OF CHEMICAL PHYSICS, vol. 124, pp. 116102-1-116102-2, ISSN:0021-9606, American Institute of Physics:2 Huntington Quadrangle, Suite 1NO1:Melville, NY 11747:(800)344-6902, (631)576-2287, EMAIL: subs@aip.org, INTERNET: http://www.aip.org, Fax: (516)349-9704:
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V.M. GIORDANO; F.A. GORELLI; R. BINI (2006). Infrared study of high-pressure molecular phases of carbon dioxide. LOW TEMPERATURE PHYSICS, vol. 32, pp. 1067-1071, ISSN:1063-777X, American Institute of Physics:2 Huntington Quadrangle, Suite 1NO1:Melville, NY 11747:(800)344-6902, (631)576-2287, EMAIL: subs@aip.org, INTERNET: http://www.aip.org, Fax: (516)349-9704:
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M. SANTORO; F.A. GORELLI; R. BINI; G. RUOCCO; S. SCANDOLO; W. CRICHTON (2006). Amorphous silica-like carbon dioxide. NATURE, vol. 41, pp. 857-860, ISSN:0028-0836
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D. Chelazzi; M. Ceppatelli; M. Santoro; R. Bini; V. Schettino (2005). Pressure induced polymerization in solid ethylene. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 109, pp. 21658-21663, ISSN:1520-6106
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V. Schettino; R. Bini; M. Ceppatelli; L. Ciabini; M. Citroni (2005). Chemical reactions at very high pressure. In: V. Schettino; R. Bini; M. Ceppatelli; L. Ciabini; M. Citroni. Advances in Chemical Physics, pp. 105-242 Wiley.
V.Latussek; C.R.Becker; G.Landwehr; R Bini; L.Ulivi (2005). Deformation potentials of the semimetal HgTe. PHYSICAL REVIEW. B, CONDENSED MATTER AND MATERIALS PHYSICS, vol. 71, pp. 125305-1-125305-7, ISSN:1098-0121
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L. Ciabini; F.A Gorelli; M. Santoro; R. Bini; V. Schettino; M. Mezouar (2005). High-pressure and high-temperature equation of state and phase diagram of solid benzene. PHYSICAL REVIEW. B, CONDENSED MATTER AND MATERIALS PHYSICS, vol. 72, pp. 094108-1-094108-7, ISSN:1098-0121
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M. CITRONI; M. CEPPATELLI; R. BINI; AND V. SCHETTINO (2005). High-pressure reactivity of propene.. THE JOURNAL OF CHEMICAL PHYSICS, vol. 123, pp. 194510-1-194510-9, ISSN:0021-9606, American Institute of Physics:2 Huntington Quadrangle, Suite 1NO1:Melville, NY 11747:(800)344-6902, (631)576-2287, EMAIL: subs@aip.org, INTERNET: http://www.aip.org, Fax: (516)349-9704:
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C. R. BECKER; V. LATUSSEK; G. LANDWEHR; R. BINI; AND L. ULIVI (2005). Pressure Dependence of Intersubband Transitions inHgTe/Hg0.3Cd0.7Te Superlattices. JOURNAL OF ELECTRONIC MATERIALS, vol. 34, pp. 811-814, ISSN:0361-5235, Minerals, Metals and Materials Society:184 Thorn Hill Road:Warrendale, PA 15086:(800)759-4867, (724)776-9000, EMAIL: subscriptions@tms.org, INTERNET: http://www.tms.org, Fax: (724)776-3770:
D.Chelazzi; M.Ceppatelli; M.Santoro; R.Bini; V.Schettino (2004). High-pressure synthesis of crystalline polyethylene using optical catalysis. NATURE MATERIALS, vol. 3, pp. 470-475, ISSN:1476-1122
DOI
R. BINI (2004). Laser-assisted high pressure chemical reactions.. ACCOUNTS OF CHEMICAL RESEARCH, vol. 37, pp. 95-101, ISSN:1520-4898, American Chemical Society:1155 Sixteenth Street Northwest:Washington, DC 20036:(800)227-5558, EMAIL: service@acs.org, INTERNET: http://www.pubs.acs.org, Fax: (614)447-3671:
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F.A. GORELLI; V.M. GIORDANO; P.R. SALVI; R. BINI (2004). Linear carbon dioxide in the high-pressure high-temperature crystalline phase IV.. PHYSICAL REVIEW LETTERS, vol. 93, pp. 2050503-1-2050503-4, ISSN:0031-9007
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M. CITRONI; M. CEPPATELLI; R. BINI; V. SCHETTINO (2003). The high-pressure chemistry of butadiene crystal. THE JOURNAL OF CHEMICAL PHYSICS, vol. 118, pp. 1815-1820, ISSN:0021-9606, American Institute of Physics:2 Huntington Quadrangle, Suite 1NO1:Melville, NY 11747:(800)344-6902, (631)576-2287, EMAIL: subs@aip.org, INTERNET: http://www.aip.org, Fax: (516)349-9704:
V. SCHETTINO; R. BINI (2003). Molecules under extreme conditions: chemical reactions at high pressure. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, vol. 5, pp. 1951-1965, ISSN:1463-9076, Royal Society of Chemistry:Thomas Graham House, Science Park, Cambridge CB4 0WF United Kingdom:011 44 1223 432360, EMAIL: sales@rsc.org, INTERNET: http://www.rsc.org, http://www.chensoc.org, Fax: 011 44 1223 423429:
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M. CEPPATELLI; M. SANTORO; R. BINI; V. SCHETTINO (2003). High pressure reactivity of solid furan probed by infrared and Raman spectroscopy.. THE JOURNAL OF CHEMICAL PHYSICS, vol. 118, pp. 1499-1506, ISSN:0021-9606, American Institute of Physics:2 Huntington Quadrangle, Suite 1NO1:Melville, NY 11747:(800)344-6902, (631)576-2287, EMAIL: subs@aip.org, INTERNET: http://www.aip.org, Fax: (516)349-9704:
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M. CITRONI; M. CEPPATELLI; R. BINI; V. SCHETTINO (2003). Phase-diagram and crystal phases of trans-1,3 butadiene probed by FTIR and Raman spectroscopy. CHEMICAL PHYSICS LETTERS, vol. 367, pp. 186-192, ISSN:0009-2614, Elsevier BV:PO Box 211, 1000 AE Amsterdam Netherlands:011 31 20 4853757, 011 31 20 4853642, 011 31 20 4853641, EMAIL: nlinfo-f@elsevier.nl, INTERNET: http://www.elsevier.nl, Fax: 011 31 20 4853598:
M. SANTORO; L. CIABINI; R. BINI; V. SCHETTINO (2003). High pressure polymerisation of phenylacetylene and of the benzene and acetylene moieties.. JOURNAL OF RAMAN SPECTROSCOPY, vol. 34, pp. 557-566, ISSN:0377-0486, John Wiley & Sons Limited:1 Oldlands Way, Bognor Regis, P022 9SA United Kingdom:011 44 1243 779777, EMAIL: cs-journals@wiley.co.uk, INTERNET: http://www.wiley.co.uk, Fax: 011 44 1243 843232:
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M.SANTORO; M.CEPPATELLI; R.BINI; V.SCHETTINO (2003). High pressure photo-chemistry of furan crystal.. THE JOURNAL OF CHEMICAL PHYSICS, vol. 118, pp. 8321-8325, ISSN:0021-9606, American Institute of Physics:2 Huntington Quadrangle, Suite 1NO1:Melville, NY 11747:(800)344-6902, (631)576-2287, EMAIL: subs@aip.org, INTERNET: http://www.aip.org, Fax: (516)349-9704:
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L. Ciabini; M. Santoro; R. Bini; V. Schettino (2002). High pressure photoinduced ring opening of benzene. PHYSICAL REVIEW LETTERS, vol. 88, pp. 085505-1-085505-4, ISSN:0031-9007
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L. Ciabini; M. Santoro; R. Bini; V. Schettino (2002). High pressure reactivity of solid benzene probed by infrared spectroscopy. THE JOURNAL OF CHEMICAL PHYSICS, vol. 116, pp. 2928-2935, ISSN:0021-9606
M. Citroni; M. Ceppatelli; R.Bini; V. Schettino (2002). Laser-induced selectivity for dimerization versus polymerization of butadiene under pressure. SCIENCE, vol. 295, pp. 2058-2060, ISSN:0036-8075
MORONI L.; CEPPATELLI M.; C.GELLINI; P. SALVI; R.BINI (2002). Excitation of crystalline all-trans retinal under pressure. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, vol. 4, pp. 5761-5767, ISSN:1463-9076
G. CARDINI; V. SCHETTINO; R. BINI; M. CAPECCHI (2001). THE VIBRATIONAL SPECTRA OF PHOSPHOROUS OXYNITRIDE AT HIGH PRESSURES. In: Capecchi, M; Bini, R; Cardini, G; Schettino, V. STUDIES IN SURFACE SCIENCE AND CATALYSIS vol. 140, pp. 103-109 Gamba, A; Colella, C; Coluccia, S, ISBN:0-444-50632-2.
L. Ciabini; M. Santoro; R.Bini; V. Schettino (2001). High pressure crystal phases of solid benzene probed by infrared spectroscopy. THE JOURNAL OF CHEMICAL PHYSICS, vol. 115, pp. 3742-3749, ISSN:0021-9606
M. Santoro; F.A. Gorelli; L. Ulivi; R.Bini; H.J. Jodl (2001). Antiferromagnetism in the high-pressure phases of solid oxygen: Low-energy electronic transitions. PHYSICAL REVIEW. B, CONDENSED MATTER AND MATERIALS PHYSICS, vol. 64, pp. 64428-1-64428-7, ISSN:1098-0121
M. Santoro; F.A. Gorelli; L. Ulivi; R. Bini; S. Medvedev; A.P. Brodyansky and H.J. Jodl (2001). FTIR study of electronic transitions in solid oxygen at high pressure and low temperature. JOURNAL OF LOW TEMPERATURE PHYSICS, vol. 122, pp. 323-330, ISSN:0022-2291
F. A. Gorelli; M. Santoro; L. Ulivi; R. Bini (2001). Spectroscopic study of the epsilon phase of solid oxygen. PHYSICAL REVIEW. B, CONDENSED MATTER AND MATERIALS PHYSICS, vol. 63, pp. 104110-1-104110-11, ISSN:1098-0121
F. A. Gorelli; M. Santoro; L. Ulivi; R. Bini (2000). Antiferromagnetic order in the delta phase of solid oxygen. PHYSICAL REVIEW. B, CONDENSED MATTER AND MATERIALS PHYSICS, vol. 62, pp. 3604-3607, ISSN:1098-0121
M. Ceppatelli; M. Santoro; R. Bini; V. Schettino (2000). Fourier transform infrared study of the pressure and laser induced polymerization of solid acetylene. THE JOURNAL OF CHEMICAL PHYSICS, vol. 113, pp. 5991-6000, ISSN:0021-9606
R. Bini; L. Ulivi; J. Kreutz; H. J. Jodl (2000). High-pressure phases of solid nitrogen by Raman and infrared spectroscopy. THE JOURNAL OF CHEMICAL PHYSICS, vol. 112, pp. 8522-8529, ISSN:0021-9606
A. De Lorenzi; S. Giorgianni; R. Bini (2000). High-resolution FTIR spectrum of vinyl chloride: rovibrational analysis of the v(10) and v(11) fundamental bands. MOLECULAR PHYSICS, vol. 98, pp. 355-362, ISSN:0026-8976
F. A. Gorelli; M. Santoro; L. Ulivi; R. Bini (1999). Intermolecular interactions in the epsilon phase of solid oxygen studied by infrared spectroscopy. PHYSICA. B, CONDENSED MATTER, vol. 265, pp. 49-53, ISSN:0921-4526
A. De Lorenzi; S. Giorgianni; R. Bini (1999). High-resolution FTIR spectroscopy of the C-Cl stretching mode of vinyl chloride. MOLECULAR PHYSICS, vol. 96, pp. 101-108, ISSN:0026-8976
L. Ulivi; R. Bini; M. Santoro (1999). Extended spectroscopic studies of Ar(H2)2 at high pressure and low temperature. PHYSICA. B, CONDENSED MATTER, vol. 265, pp. 39-48, ISSN:0921-4526
F. A. Gorelli; M. Santoro; L. Ulivi; R. Bini (1999). High-pressure and low-temperature infrared study of solid oxygen: Evidence of a new crystal structure. PHYSICAL REVIEW. B, CONDENSED MATTER AND MATERIALS PHYSICS, vol. 60, pp. 6179-6182, ISSN:1098-0121
L. Ulivi; R. Bini; P. Loubeyre; R. LeToullec; H.J. Jodl (1999). Spectroscopic studies of the Ar(H2)2 compound crystal at high pressure and low temperatures. PHYSICAL REVIEW. B, CONDENSED MATTER AND MATERIALS PHYSICS, vol. 60, pp. 6502-6512, ISSN:1098-0121
F. A. Gorelli; M. Santoro; L. Ulivi; R. Bini (1999). The epsilon phase of solid oxygen: Evidence of an O-4 molecule lattice. PHYSICAL REVIEW LETTERS, vol. 83, pp. 4093-4096, ISSN:0031-9007
R. Bini; M. Jordan; L. Ulivi; H. J. Jodl (1998). Infrared and Raman studies on high pressure phases of solid N2. An intermediate structural modification between epsilon and delta phases. THE JOURNAL OF CHEMICAL PHYSICS, vol. 108, pp. 6849-6856, ISSN:0021-9606
J. Haines; J.M. Leger; R. Chateau; R. Bini; L. Ulivi (1998). Ferroelastic phase transition in rutile-type germanium dioxide at high pressure. PHYSICAL REVIEW. B, CONDENSED MATTER AND MATERIALS PHYSICS, vol. 58, pp. 2909-2912, ISSN:1098-0121
C BUNGENSTOCK; T TRSTER; W B HOLZAPFEL; R BINI; L ULIVI; S. CAVALIERI (1998). Study of the energy level scheme of Pr3+:LaOCl under pressure. JOURNAL OF PHYSICS. CONDENSED MATTER, vol. 10, pp. 9329-9339, ISSN:0953-8984, IOP Publishing Limited:Dirac House, Temple Back, Bristol BS1 6BE United Kingdom:011 44 117 9297481, EMAIL: custserv@iop.org, INTERNET: http://www.iop.org, Fax: 011 44 117 9294318:
L. Ulivi; R. Bini; H.J. Jodl; P. Loubeyre; R. Le Toullec; F. Datchi (1998). Infrared studies of Ar(H2)2 at low temperature and high pressure. JOURNAL OF LOW TEMPERATURE PHYSICS, vol. 111, pp. 703-708, ISSN:0022-2291
M. BECUCCI; E. CASTELLUCCI; R. BINI; B. ECKERT; H. JODL (1997). Mode assignment of Sulphur α-S8 by polarized Raman and FTIR studies at low temperatures. JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL, vol. 101, pp. 2132-2137, ISSN:1520-6106
DOI
Accesso ONLINE all'editore
R. Bini; R. Ballerini; G. Pratesi; H. J. Jodl (1997). Experimental set-up for Fourier Transform Infrared spectroscopy studies in condensed matter at high pressure and low temperature. REVIEW OF SCIENTIFIC INSTRUMENTS, vol. 68, pp. 3154-3160, ISSN:0034-6748
R. Bini; G. Pratesi (1997). High-pressure infrared study of solid methane: Phase diagram up to 30 GPa. PHYSICAL REVIEW. B, CONDENSED MATTER, pp. 14800-14809, ISSN:0163-1829
R. Bini; S. Califano; B. Eckert; H. J. Jodl (1997). Temperature dependence of the vibrational relaxation processes in natural and isotopically pure 32S8 : effect of the isotopic impurities on infrared phonon lifetimes. THE JOURNAL OF CHEMICAL PHYSICS, vol. 106, pp. 973-986, ISSN:0021-9606
E.Quirico;B.Schmitt;R.Bini;P.Salvi (1996). Spectroscopy of some ices of astrophysical interest: SO2, N2 and N2:CH4 mixtures. PLANETARY AND SPACE SCIENCE, vol. 44, pp. 973-986, ISSN:0032-0633
R. Bini (1996). High resolution infrared study of the translational lattice modes in alpha-N2 single crystals. THE JOURNAL OF CHEMICAL PHYSICS, vol. 104, pp. 4365-4370, ISSN:0021-9606
R. Bini ; J. Ebenhoch; M. Fanti; P.W. Fowler; S. Leach; G. Orlandi; Ch. Ruchardt; J.P.B. Sandall; F. Zerbetto (1996). The vibrational spectroscopy of C60H36: an experimental and theoretical study. CHEMICAL PHYSICS, vol. 232, pp. 75-94, ISSN:0301-0104
B. Caldarone; C. Taiti; R. Bini; V. Schettino (1995). Vibrational relaxation in disordered 1, 4-dihalobenzenes. THE JOURNAL OF CHEMICAL PHYSICS, vol. 102, pp. 6653-6659, ISSN:0021-9606
R.Bini;L.Ulivi;H.J.Jodl;P.Salvi (1995). High pressure crystal phases of solid CH4 probed by Fourier transform infrared spectroscopy. THE JOURNAL OF CHEMICAL PHYSICS, vol. 103, pp. 1353-1360, ISSN:0021-9606
C. Panero; R. Bini; V. Schettino (1994). Vibron dynamics in Naphthalene crystal. THE JOURNAL OF CHEMICAL PHYSICS, vol. 100, pp. 7938-7944, ISSN:0021-9606
G. Cardini; R. Bini; P. R. Salvi; V. Schettino; M. L. Klein; R. M. Strongin; L. Brard; A. B. Smith III (1994). Infrared spectrum of two fullerene derivatives: C60O and C61H2. THE JOURNAL OF PHYSICAL CHEMISTRY, vol. 98, pp. 9966-9971, ISSN:0022-3654
B. Eckert; R. Bini; H. J. Jodl; S. Califano (1994). High resolution infrared spectra of the v3 vibron in natural sulfur and in the isotopically pure 32S crystal. THE JOURNAL OF CHEMICAL PHYSICS, vol. 100, pp. 912-916, ISSN:0021-9606
L. Poletti; R. Bini; V. Schettino (1994). Vibrational relaxation of lattice phonons in CS2 crystal. CHEMICAL PHYSICS LETTERS, vol. 222, pp. 239-244, ISSN:0009-2614
V. SCHETTINO; PR. SALVI; R. BINI; G. CARDINI (1994). On the vibrational assignment of fullerene C<SUB>60</SUB>. THE JOURNAL OF CHEMICAL PHYSICS, vol. 101, pp. 11079-11081, ISSN:0021-9606, American Institute of Physics:2 Huntington Quadrangle, Suite 1NO1:Melville, NY 11747:(800)344-6902, (631)576-2287, EMAIL: subs@aip.org, INTERNET: http://www.aip.org, Fax: (516)349-9704:
R.Bini;P.Salvi;V.Schettino;H.J.Jodl (1993). The spectroscopy and relaxation dynamics of three-phonon bound states in crystal CO2. THE JOURNAL OF CHEMICAL PHYSICS, vol. 98, pp. 164-177, ISSN:0021-9606
R.Bini;P.Procacci;P.Salvi;V.Schettino (1993). The far infrared spectrum of C60. THE JOURNAL OF PHYSICAL CHEMISTRY, vol. 97, pp. 10580-10584, ISSN:0022-3654
R.Bini;V.T.Bich;P.Salvi,G.Marconi (1992). Multiphoton absorption in crystalline biphenylene. JOURNAL OF LUMINESCENCE, vol. 53, pp. 529-532, ISSN:0022-2313
R. Bini; H. J. Jodl; S. Califano (1992). Relaxation processes of the infrared-active lattice phonons of crystalline CO2. PHYSICAL REVIEW. B, CONDENSED MATTER, vol. 45, pp. 5244-5250, ISSN:0163-1829
P. FOGGI; R. BINI; E. CASTELLUCCI; G. MARCONI (1992). Measurement of the 3rd-order nonresonant susceptibility of the phtalate ion in solution amd in a C6H4COOH.COOK crystal.. JOURNAL OF LUMINESCENCE, vol. 53 (6), pp. 541-545, ISSN:0022-2313
R.Bini;P.Salvi;V.Schettino;H.J.Jodl;N.Orlic (1992). Vibrational relaxation of three-phonon bound states in crystal CO2. JOURNAL OF MOLECULAR STRUCTURE, vol. 266, pp. 165-170, ISSN:0022-2860
Bini R.; Foggi P.; Castellucci E.; Destri S. (1991). CHI(3) evaluation of poly-3-decyl-thiophene (PAT) by CARS spectroscopy.. In: Materials for Photonic Devices, Taormina, Italy, 27-31 may 1991, pp. 388-391.
R. Bini; P. Foggi; R. G. Della Valle (1991). Vibrational analysis of the carbon-hydrogen stretching overtones in pyridine and 2 6-lutidine. THE JOURNAL OF PHYSICAL CHEMISTRY, vol. 95, pp. 3027-3031, ISSN:0022-3654
R.Bini;P.Salvi;V.Schettino;H.J.Jodl (1991). Triphonons in crystal CO2. PHYSICS LETTERS A, vol. 157, pp. 273-282, ISSN:0375-9601
R.Bini;P.Foggi;P.Salvi;V.Schettino (1990). FTIR study of vibrational relaxation in KClO4 crystal. THE JOURNAL OF PHYSICAL CHEMISTRY, vol. 94, pp. 6653-6658, ISSN:0022-3654
V.T.Bich;R.Bini;P.Salvi;G.Marconi (1990). Two-photon spectroscopy of antiaromatic molecules:the case of biphenylene. CHEMICAL PHYSICS LETTERS, vol. 175, pp. 413-418, ISSN:0009-2614
R.Bini;P.Foggi;P.Salvi;R.Simone;V.Schettino (1990). Vibrational relaxation of davydov components of the 940 cm-1 mode in KClO4 crystal. JOURNAL OF MOLECULAR STRUCTURE, vol. 219, pp. 43-48, ISSN:0022-2860
R. Bini; P. Foggi; R. G. Della Valle (1990). High overtones investigation of non-equivalent C-H bonds in pyridine and 2, 6-lutidine by thermal lensing spectroscopy. JOURNAL OF MOLECULAR STRUCTURE, vol. 218, pp. 117-122, ISSN:0022-2860
R. Bini; P. Foggi; N. Q. Liem; P. R. Salvi (1988). Lower excited states of sulfur S8: a two-photon study by the thermal lensing method. CHEMICAL PHYSICS LETTERS, vol. 151, pp. 236-242, ISSN:0009-2614
P.FOGGI; PR. SALVI; R.BINI; E.CASTELLUCCI (1988). Two-Photon absorption of liquid pyridine: a study using thermal lensing and CARS spectroscopy.. JOURNAL OF MOLECULAR STRUCTURE, vol. 175, pp. 147-152, ISSN:0022-2860
P.R.SALVI; P.FOGGI; R.BINI; E.CASTELLUCCI (1987). Two-photon spectrum of liquid pyridine by thermal lensing technique.. CHEMICAL PHYSICS LETTERS, vol. 141, pp. 417-422, ISSN:0009-2614
Roberto BINI
Curriculum
ACADEMIC AND SCIENTIFIC CAREER
Education:
Degree in Chemistry
at the University of Firenze (1986),
PhD in Chemistry
(curriculum Solid State Chemical-Physics) at the University of Firenze (1988-1991),
Since October, 1st, 1991
Researcher
(Chemical-Physics C02X) at the Chemistry Department of the University of Firenze.
Since November 2000
associate Professor
(Chemical-Physics CHIM02) at the Chemistry Department of the University of Firenze.
Since 2000 he is in charge of the “
Matter Under Extreme Conditions
” research group at the European Laboratory for non-linear Spectroscopy (LENS).
Since 2010 he is member of the
LENS Directive Council
as representative of the University of Firenze.
He is in charge of the following courses for the degree (both first and second level) in Chemistry: 2000 - : Spettroscopia Molecolare; 2001 - : Laboratorio Di Chimica Fisica I; 2009 - : Metodi sperimentali di indagine strutturale e dinamica.
Director of several degree thesis in Chemistry and PhD thesis in “Material Science” and “Atomic and Molecular Spectroscopy” and supervisor of several post-doctoral projects.
OTHER ACTIVITIES:
Member of the review panel (2006 and 2011) evaluating the high pressure beamlines (ID16 e ID27) at the European Synchrotron Research Facility (ESRF);
Member of the Physical Chemistry Directorate steering committee of the Deep Carbon Observatory (
https://dco.gl.ciw.edu/
).
Coordinator of several research projects financed with both public and private fundings.
AWARDS:
San Valentino d’Oro XXXI for the scientific Research (2000);
“Le Scienze” magazine prize for Chemistry (2001);
Medaglia del Presidente della Repubblica for the experimental results obtained in the high pressure studies concerning the electronic properties and the reactivity of molecular crystals (2001).
RESEARCH ACTIVITY
His research activity has experimental character and regards the study of structural and dynamic properties of molecular systems in condensed phases by using linear and non-linear optical techniques. In the last years his attention was devoted to understand the microscopic mechanisms of reactive processes tuned by pressure in pure molecular fluids and crystals by using the Diamond Anvil Cell (DAC) technique. The main recent achievements can be summarized as:
coupling of the DAC technique to a FTIR spectrometer performing for the first time infrared absorption experiments as a function of pressure (P≤1 Mbar) and temperature (15-350 K).
monitoring of the evolution of pressure induced phase changes, molecular transformations and solid state chemical reactions in simple model molecular systems (N
2
, O
2
, C
2
H
2
);
correlation of the structural and dynamic crystal properties to the reactive processes, for the first time the role of lattice phonons in triggering chemical reactions is highlighted;
application of non-linear optical techniques to samples in the DAC allowing a direct characterization of the electronic properties as a function of pressure;
combined use of light and pressure to induce and drive the chemical reactivity at high pressure unveiling the role of electronic excited states in high-pressure reactivity;
application of these methods to amorphyzation (benzene, CO
2
) polymerization (polyethylene, polybutadiene, polyacetilene) and reactions in mixtures (fluid, heterogeneous and clathrate hydrates) containing water or simple alcohols for the synthesis of hydrogen.
He published as main author or co-author more than 100 articles in the main international journals and peer reviewed books dealing with chemical-physics and condensed matter physics arguments.
